The 03 can store four transmitters. Take all the transmitters to the dealer, and he will clear the transmitters programmed, then program in all the ones you brought with you.
Then you'll need to do the same for the 'burb. This is assuming they use the same remotes. Also, make sure you use the remote with the most buttons for your keyring. My Z28 has an extra button for the rear hatch.
Hmmmm, I wonder if that extra button could be used on the AV? Maybe a cargo light switch?
On the Z28 there is a procedure that involves removing a fuse, using the key, putting your left leg in, and your right leg out.... It is a pain, so I just took it to the dealer. Turned out there magic box hadn't been updated, so they fopllowed the manual procedure, worked fine.
The only problems are
1. If you have both cars, you're gonna unlock both

2. The rolling codes may get out of synch. I think if you press your arm button repeatedly, it will re-sysnch. (Or maybe I'M getting this confused with my garage door opener?
Found the sequence to program a 99 Denali, it should work. It's here
http://www.automotiveforums.com/t129207.html