Just some more info, for anyone that's interested:
I was looking into the Warn unit, and found out that it's actually made by a company called SurePower. Surepower makes 2 different items that are similar:
Battery Separator / Interconnect - http://www.surepower.com/separator.html
This sounds very similar to the Painless kit mentioned above. It allows 2 batteries to be connected and charged in sequence (Primary, then Aux). The secondary battery can be used to run accessories, and the seperator cuts over and charges the Aux battery once it detects the Primary is fully charged. I'm not sure if the Painless kit can be wired to work this way, but SurePower Seperator seems to be able to use a voltage signal from the starter (or a manual switch), combined with detecting a lower charge on the Primary battery, to automatically cut-in the Aux battery for a starting assist (I only saw a manual switch option on the Painless kit for this).
Battery Isolator - http://www.surepower.com/isolator.html
It appears that this item also allows both batteries to charge simultaneously, while keeping them, and anything connected to them, isolated into 2 completely seperate circuits. It also says that it will not allow Battery #2 (Accessory Battery) to draw down Battery #1 (Primary / Starting), but no mention of the other way around, so I'm guessing the Accessory Battery can still act as an assist to the Primary if the Primary is low. This is also a completely automated unit - no switches, just the battery leads to hook up.
The Warn unit I mentioned above will NOT work with the '07+ Avalanche, as it is rated to 120Amp, but the 07+ uses a 160Amp alternator. I don't know about previous models, but there's a small electrical plug on the alternator, and if you pop it out and look at the pins on the alternator side, if there's more than 1 pin the Warn unit won't work. I've recieved some word that the 200Amp Isolator from SurePower (PN#2002, I believe) will be OK, but I also found the installation instructions here that may say differently (my '07 has the incompatible plug as indicated on p. 3 of the following PDF).
http://www.donrowe.com/battery_isolator/isolator_instructions.pdf
That led me to Smith Auto Electric, which had this page up:
http://www.smithae.com/surepower.html
"The difference in whether to use a battery isolator or battery separator will depend on whether your alternator has internal or external voltage sensing. Many of the newer alternators are internal sensing and so cannot be used with an isolator, because of the loss of approximately 1 volt across the diodes, In these cases you would use a battery separator."
Also note - I was told by my local dealer that the Painless kit would NOT work w/ an '07, though he also said that he's used Painless in the past and likes thier stuff. I'm not sure why, though...
So, my next step will be to call Smith AE and see what they recommend.